Veolia Water Technologies & Solutions

Ion Exchange Membranes

Veolia's ion exchange membranes are homogeneous ion exchange films cast in sheet form on reinforcing synthetic fabrics such as polypropylene and polyester cloth. The membranes are typically used in Veolia's Electrodialysis (ED), Bipolar Electrodialysis (BPED) and Electrodialysis Reversal (EDR) stacks but are also available for sale individually.

Veolia's membranes are made with monomer formulations developed by our membrane chemists cast continuously on various support structures. They are each selective for allowing either anions or cations to pass through them.

Overview

Veolia’s proprietary membranes aim to provide optimal performance and tier 1 quality for all applications, combining lower power consumption with high product purity.

Features & Benefits

  • Low electrical resistance
  • High permselectivity
  • Rugged construction and high burst strength
  • Excellent long-term stability up to 70°C
  • Long-term resistance to aqueous acid and base solutions
  • High dimensional stability
  • High resistance to fouling by organic materials

How It Works

Membranes by Application:

Organic Fouling Resistant Membranes
AR103 and CR61 provide stability in high pH environments where aggressive cleaning with caustic solutions is needed along with organic material fouling resistance. These membrane chemistries have been used for more than 50 years for applications in the food and beverage industry, most prominently in the demineralization of cheese whey,

Standard Water Membranes:
Veolia's AR204 and CR67 membranes have the widest total footprint globally. They have been the primary membrane used in water desalination electrodialysis applications for 30 years. They are a cost-effective, scaling resistant membrane with resistance to chlorine, are NSF approved, and in water desalination applications can have a lifetime of 15 years or more. They can also be used for low organic fouling process applications.

Bipolar Membranes:
Veolia's Bipolar membranes are used in electrodialysis applications where salts are converted into acid and caustic product streams or where pH of process solutions can be adjusted. These membranes have two layers; one cation-selective and one anion-selective layer. The AR103 and CR63 are the primary options for the layers of the bipolar membrane.The anion layer is treated with a catalyst to aid in the water splitting function of the membrane.

Acid-Blocking Anion Membranes:
In 3C-BPED applications, where separate acid and base streams are generated, the use of standard anion exchange membranes limits the concentration of acid that can be achieved due to the free movement of protons (H+) from the high concentration acid stream through the anion membrane back into the dilute salt stream. Veolia has developed two types of acid-blocking membranes that limit this transfer and allow for higher concentrations in the acid and base stream and/or allow operation at a higher current efficiency. The AR118 chemistry is specifically designed for multi-valent anions like sulphate, the AR119 chemistry is most suitable for mono-valent anions like chlorides.

High pH Anion Membranes:
Veolia's AR908 membrane is a versatile anion exchange membrane that has been used by some of our largest EDR installations for drinking water and wastewater desalination. It allows for cleaning with high pH solutions which the AR204 does not. However, its resistance to chlorine is lower, so there can be a tradeoff depending on the specific application. The caustic resistance also makes it a cost-effective alternative to the AR103 membrane for process demineralization applications.

 

Membrane Innovation:

Nonwoven Cloth Membranes:
To improve performance of our ion exchange membranes, we discontinued use of a woven acrylic cloth and replaced it with a nonwoven polyester cloth. First, the nonwoven cloth membranes have lower electrical resistance. This means that when used, the voltage required to achieve a target product TDS can be lower. This can result in lower power consumption by the ED or EDR plant. Since the membranes are made of a nonwoven cloth, they will not generate “strings” hanging on the exterior of the stack as the edge of the membranes become dry, as happens with the use of woven cloths.

Thinner Membranes:
As part of the new generation of ED and EDR stack designs, Veolia created the V series with thinner membranes that fit in our recessed spacer design to further improve electrical resistance for more efficient ED and EDR operation. These membranes can also be used in existing MK4 stack hardware to provide lower power consumption and/or expanded capacity. 750 cells of membranes will fit in the space that 600 cells of the thicker membranes occupy.

Resources

Membrane Selection Guide

We offer membranes in various configurations suitable for ED, BPED, and EDR stacks, plus uncut or blank boards for customized applications. The fact sheet provides membrane properties, selection guides, and material descriptions, detailing the main available configurations.

Download Ion Exchange Membranes Fact Sheet

Certifications & Compliance:

  • NSF 61 - Drinking Water
  • 21CFR175,176,177,178,182 – Food Contact Materials
  • EU 1935/2004 – Food Contact Materials
  • EU 10/2001 - Food Contact Materials
  • BSE/TSE EMEA/410/1 – No Materials of Animal Origin

For further details and specific certifications, please download and the product fact sheet and/or product declaration.

 

Membrane Fact Sheets:

AR103P Fact Sheet
An anion-selective ion exchange membrane typically used for applications with high organic material content and applications where high pH cleaning is required

AR204E Fact Sheet
An anion-selective ion exchange membrane typically used in water treatment applications

AR204T Fact Sheet
An anion-selective ion exchange membrane typically used in water treatment applications

AR908T Fact Sheet
An anion-selective ion exchange membrane typically used in water treatment applications or process applications where high pH cleaning is required

CR61P Fact Sheet
A cation-selective ion exchange membrane typically used for applications with high organic material content and applications where high pH cleaning is required

CR67E Fact Sheet
A cation-selective ion exchange membrane typically used in water treatment applications

CR67T Fact Sheet
A cation-selective ion exchange membrane typically used in water treatment applications